1265602-80-9Relevant academic research and scientific papers
One-Pot Electrochemical Nickel-Catalyzed Decarboxylative Sp2-Sp3 Cross-Coupling
Koyanagi, Takaoki,Herath, Ananda,Chong, Ashley,Ratnikov, Maxim,Valiere, Andrew,Chang, Jim,Molteni, Valentina,Loren, Jon
supporting information, p. 816 - 820 (2019/01/30)
A one-pot electrochemical nickel-catalyzed decarboxylative sp2-sp3 cross-coupling reaction has been developed using redox-active esters prepared in situ from alkyl carboxylates and N-hydroxyphthalimide tetramethyluronium hexafluorophosphate (PITU). This undivided cell one-pot method enables C-C bond formation using inexpensive, benchtop-stable reagents with isolated yields up to 95% with good functional group tolerance, which includes nitrile, ketone, ester, alkene and selectivity over other aromatic halogens.
Csp3-Csp2 palladium-catalyzed cross-coupling reaction of trialkylbismuth reagents with aryl, heteroaryl, and vinyl halides and triflates
Gagnon, Alexandre,Albert, Vincent,Duplessis, Martin
experimental part, p. 2936 - 2940 (2011/02/28)
The palladium-catalyzed cross-coupling reaction of trialkylbismuth reagents with aryl and heteroaryl halides and triflates is reported. Moderate to good yields were obtained for the transfer of primary alkyl groups. The reaction tolerates numerous functional groups on the electrophilic and nucleophilic partners. The cross-coupling of -bromostyrene with tris(1,3-dioxan-2-ylethyl) bismuth is also reported. Georg Thieme Verlag Stuttgart - New York.
