126577-50-2Relevant academic research and scientific papers
NEW APPROACHES FOR ASYMMETRIC SYNTHESIS OF SULFOXIDES
Kagan, Henry B.,Rebiere, Francois,Samuel, Odile
, p. 89 - 110 (2007/10/02)
Recent progress in asymmetric oxidation of sulfides is passed in review, and the various possibilities of using chiral sulfites for asymmetric synthesis of sulfoxides are discussed.
A General Route to Enantiomerically Pure Sulfoxides from a Chiral Sulfite
Rebiere, F.,Samuel, O.,Ricard, L.,Kagan, H.B.
, p. 5991 - 5999 (2007/10/02)
Enantiomerically pure cyclic chiral sulfite (S)-7 (trans stereochemistry) has been easily obtained in two steps from (S)-ethyl lactate.This compound was found to react cleanly with many organometallics to give crystalline sulfinates with high regioselecti
