126582-12-5Relevant articles and documents
Lewis Acid-induced Ene-Cyclization of ω-Olefinic Trifluoromethyl Ketones: Access to Alicyclic Compounds bearing a CF3 Group
Abouabdellah, Ahmed,Aubert, Corinne,Begue, Jean-Pierre,Bonnet-Delpon, Daniele,Guilhem, Jean
, p. 1397 - 1403 (2007/10/02)
Several catalysts (Me2AlCl, MeAlCl2, EtAlCl2 and TiCl4) for the ene carbocyclization of olefinic trifluoromethyl ketonic compounds have been compared.Thus, five-, six-, seven- and eight-membered-ring compounds were obtained.Olefin regiochemistry and stere