126583-97-9Relevant academic research and scientific papers
Gold catalysis: Deuterated substrates as the key for an experimental insight into the mechanism and selectivity of the phenol synthesis
Hashmi, A. Stephen K.,Rudolph, Matthias,Siehl, Hans-Ullrich,Tanaka, Masato,Bats, Jan W.,Frey, Wolfgang
supporting information; experimental part, p. 3703 - 3708 (2009/04/17)
The second phase of the gold-catalyzed phenol synthesis, the ring opening of the intermediate arene oxide, follows general acid catalysis. The product selectivity is determined by the substrate only and can be explained by the stability of the intermediat
