126605-22-9

Basic information

• Product Name: METOLACHLOR DESCHLORO
• Synonyms: METOLACHLOR DESCHLORO;Metolachlor deschloro, 100 μg /μL in Acetonitrile
• CAS NO: 126605-22-9
• Molecular Formula: C₁₅H₂₃NO₂
• Molecular Weight: 249.352
• Mol File: 126605-22-9.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 368.7±37.0 °C(Predicted)
• Appearance: /
• Density: 1.011±0.06 g/cm3(Predicted)
• PKA: 1.63±0.50(Predicted)
• CAS DataBase Reference: METOLACHLOR DESCHLORO(CAS DataBase Reference)
• NIST Chemistry Reference: METOLACHLOR DESCHLORO(126605-22-9)
• EPA Substance Registry System: METOLACHLOR DESCHLORO(126605-22-9)

Safety Data

• Hazardous Substances Data: 126605-22-9(Hazardous Substances Data)

Upstream product

• 51218-45-2 2-chloro-6'-ethyl-N-(2-methoxy-1-methylethyl)acet-o-toluidide 

Relevant articles and documents

Catalytic intramolecular participation of amide group in the acid hydrolysis of methyl ether linkage

Evidence for the acid catalyzed hydrolysis or methyl ether linkage assisted by the neighboring amide function was obtained. The hydrolysis rate of 1 to 3 was measured at least 1.7 x 103 fold higher than that of the reference compound 5. The values of thermodynamic parameters suggest that the participation of neighboring amide group in 1 is accompanied by a lower activation enthalphy with respect to the unassisted reaction in 5. Experimental evidence, such as the kinetic isotope ratio, the positive Φ value of Bunnett-Olsen equation and ΔS++ value suggests an A2 mechanism.