1266339-05-2

Basic information

• Product Name: (+)-2-fluoro-5,5-dimethylcyclohexanone
• Synonyms: (+)-2-fluoro-5,5-dimethylcyclohexanone
• CAS NO: 1266339-05-2
• Molecular Weight: 144.189
• Mol File: 1266339-05-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+)-2-fluoro-5,5-dimethylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-2-fluoro-5,5-dimethylcyclohexanone(1266339-05-2)
• EPA Substance Registry System: (+)-2-fluoro-5,5-dimethylcyclohexanone(1266339-05-2)

Safety Data

• Hazardous Substances Data: 1266339-05-2(Hazardous Substances Data)

Upstream product

• 2979-19-3 3,3-dimethylcyclohexanone 

Relevant articles and documents

Enantioselective organocatalytic α-fluorination of cyclic ketones

The first highly enantioselective α-fluorination of ketones using organocatalysis has been accomplished. The long-standing problem of enantioselective ketone α-fluorination via enamine activation has been overcome via high-throughput evaluation of a new library of amine catalysts. The optimal system, a primary amine functionalized Cinchona alkaloid, allows the direct and asymmetric α-fluorination of a variety of carbo- and heterocyclic substrates. Furthermore, this protocol also provides diastereo-, regio-, and chemoselective catalyst control in fluorinations involving complex carbonyl systems.