1266486-22-9Relevant academic research and scientific papers
Rh(I)-catalyzed formal [5 + 1]/[2 + 2 + 1] cycloaddition of 1-yne-vinylcyclopropanes and two CO units: One-step construction of multifunctional angular tricyclic 5/5/6 compounds
Lin, Mu,Li, Feng,Jiao, Lei,Yu, Zhi-Xiang
, p. 1690 - 1693 (2011/04/15)
A novel Rh(I)-catalyzed formal [5 + 1]/[2 + 2 + 1] cycloaddition of 1-yne-vinylcyclopropanes and two CO units for the construction of multifunctional angular tricyclic 5/5/6 skeletons with one or two adjacent bridgehead quaternary all-carbon stereocenters in one step has been developed. Preliminary density functional theory calculations have been carried out to investigate the reaction mechanism and the substituent effects.
