1266570-06-2Relevant academic research and scientific papers
Rhodium-catalyzed oxidative coupling/cyclization of benzamides with alkynes via C-H bond cleavage
Mochida, Satoshi,Umeda, Nobuyoshi,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
supporting information; experimental part, p. 744 - 746 (2011/01/09)
Oxidative coupling of primary, secondary, and tertiary benzamides with internal alkynes proceeds efficiently under rhodium catalysis to selectively give the corresponding 1:1 and 1:2 coupling products, accompanied by C-H and/or N-H bond cleavages. Some of the products exhibit intense fluorescence in the solid state.
