1266682-95-4Relevant academic research and scientific papers
Synthesis and crystal structures of two novel complexes with N-[2-(5-bromo-2-hydroxybenzylideneamino)ethyl]- 4-methylbenzenesulfonamide as ligand
Li, Shu-Ni,Zhai, Quan-Guo,Hu, Man-Cheng,Jiang, Yu-Cheng
, p. 12 - 16 (2011)
Two novel complexes constructed from the sulfonamide Schiff base ligand H2L, N-[2-(5-bromo-2-hydroxybenzylideneamino) ethyl]-4-methylbenzene- sulfonamide, [Cu(HL)2] (1) and [CuL(H2O)] (2) are synthesized and characterized via X-ray single-crystal diffraction, elemental analysis, FT-IR and UV-Vis. 1 and 2 both form 1-D supramolecular architectures by π-pπ stacking interactions. 1 and 2 both crystallize in monoclinic, with space group C2/c and P2/c for 1 and 2, with unit cell parameters a = 27.640(18) A, b = 7.907(5) A, c = 17.945(14) A, 7β = 118.27(2)°, V = 3454(4) A3, Z = 4 for 1, and a = 16.758(5) A, b = 7.272(2) A, c = 15.080(4) A, β = 106.334(5)°, V = 1763.6(9) A3, Z = 4 for 2. Springer Science+Business Media, LLC 2010.
