126741-75-1

Upstream product

• 693-02-7 hex-1-yne 
• 789-25-3 HSiPh₃ 
• 76-86-8 Triphenylsilyl chloride 
• 96475-96-6 1-(triphenylsilyl)-1-hexyne 

Downstream Products

• 126741-81-9 2-(triphenylsilylmethyl)hexanal 

Relevant academic research and scientific papers

Synthesis, structure, and catalytic activity of bimetallic pt II-IrIII complexes bridged by cyclooctane- 1,2-dithiolato ligands

Cationic PtIIIrIII heterobimetallic complexes bridged by cyclooctane-l.,2-dithiolato ligands [(PPh3)2Pt(μ 2-SRS)IrCl(η5Cp-*)[SbF6] [R = cis-C8H14 (5), trans

Gold-film-catalysed hydrosilylation of alkynes by microwave-assisted, continuous-flow organic synthesis (MACOS)

Thin gold films on the surface of glass capillaries have proven to be highly active catalysts for the rapid hydrosilylation of alkynes that are flowed through the reactor while being heated by microwave irradiation. The films are able to be reused at least five times with no loss of activity and with no detectable levels of gold showing up in the hydrosilylated products.

Novel immobilized hydrosilylation catalysts based on rhodium 1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidenes

The reactivity of a well defined Rh (I) complex, i.e. Rh(CF 3COO)(NHC)(COD) (1, NHC = 1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6- tetrahydropyrimidin-2-ylidene, COD = η4-cycloocta-1,5-diene) in the hydrosilylation of 1-alkenes, alkynes,

Rh(1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene) (COD) tetrafluoroborate, an unsymmetrical Rh-homoazallylcarbene: Synthesis, X-ray structure and reactivity in carbonyl arylation and hydrosilylation reactions

The synthesis of novel Rh(1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6- tetrahydropyrimidin-2-ylidene)(COD) tetrafluoroborate (1, COD = η4-1,5-cyclooctadiene) is described. The N-heterocyclic carbene acts as a bidentate ligand with the carbene coordinating to the Rh(I) center and an arene group acting as a homoazallyl ligand. 1 was used in various carbonyl arylation and hydrosilylation reactions allowing the formation of the desired products with unprecedented selectivity and efficiency. Thus, turn-over numbers (TONs) up to 2000 were achieved.

Highly stereoselective and efficient hydrosilylation of terminal alkynes catalyzed by [RuCl2(p-cymene)]2

(Formula presented) With [RuCl2(p-cymene)]2 as a catalyst, extremely high regio-and stereoselectivity was observed in the hydrosilylation reaction of various terminal alkynes under mild conditions to afford β-(Z)-vinylsilanes in exce

The Stereochemistry of Organometallic Compounds. XXXIV. Regioselection in the Hydroformylation of Silylalkenes

The regiochemistry of hydroformylation of alkenes can be controlled by use of bulky silyl groups attached to the alkene.Use of the t-butyldiphenylsilyl group leads to almost total regiocontrol and the method has been applied to the synthesis of aldols.