126760-72-3Relevant academic research and scientific papers
Porphyrin synthesis from nitrocompounds
Ono, Noboru,Kawamura, Hisayuki,Bougauchi, Masahiro,Maruyama, Kazuhiro
, p. 7483 - 7496 (2007/10/02)
A new porphyrin synthesis starting from nitroalkenes or their equivalents is described. For example, octaethylporphyrin, coproporphyrin, porphyrin-1,2,3,4,5,6,7,8 octapropionic acid, and 2,7,12,17 tetraarylporphyrin are prepared in good yield from readily available materials such as 1-nitropropane, nitroethane, nitromethane, and aldehydes.
Synthesis of 2,7,12,17-Tetra-arylporphyrins, New Sterically Hindered Porphyrins
Ono, Noboru,Kawamura, Hisayuki,Bougauchi, Masahiro,Maruyama, Kazuhiro
, p. 1580 - 1581 (2007/10/02)
Sterically hindered porphyrins with four bulky aryl groups in the β-positions are prepared by the reduction of ethyl 3-aryl-4-alkylpyrrole-2-carboxylate with LiAlH4 followed by treatment with an acid and oxidizing agent.
