126784-63-2Relevant academic research and scientific papers
Synthetic Approaches to Guanacastepenes. Enantiospecific Syntheses of BC and AB Ring Systems of Guanacastepenes and Rameswaralide
Srikrishna,Dethe, Dattatraya H.
, p. 165 - 168 (2007/10/03)
(Matrix presented) A simple and efficient approach for the BC and AB ring systems of the novel diterpenes guanacastepenes and rameswaralide starting from the readily and abundantly available monoterpene (R)-carvone employing RCM reaction as the key step i
An efficient ring-closing metathesis reaction of geminally disubstituted olefins using first generation Grubbs' catalyst: Enantiospecific synthesis of pacifigorgianes
Srikrishna,Dethe, Dattatraya H.
, p. 7817 - 7820 (2007/10/03)
An efficient ring closing metathesis reaction with first generation Grubbs' catalyst [PhCH=RuCl2(PCy3)2] involving geminally disubstituted olefins has been discovered. It has been extended to the enantiospecific synthesis of pacifigorgiane sesquiterpenes.
A NEW CHIRAL ROUTE TOWARD TERPENOIDS. ANNULATION OF CARVONE TO TRANS- AND CIS-FUSED BICYCLIC SYNTHONS
Gesson, Jean-Pierre,Jacquesy, Jean-Claude,Renoux, Brigitte
, p. 5853 - 5866 (2007/10/02)
Starting from carvone, 1 two consecutive alkylations at C-6 followed by an acid-catalyzed cyclization give new bicyclic ketones which are potentially useful chirons for synthesis of terpenes such as drimanes, labdanes and triterpenes.The stereoselectivity
