126784-65-4

Upstream product

• 6485-40-1 (R)-Carvone 
• 513-31-5 2-bromoallyl bromide 

Downstream Products

• 20404-65-3 (-)-(2R,4aS,8aS)-2,5,5,8a-Tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1(2H)-one 
• 110188-61-9 (5S,6S)-6-(2-bromoallyl)-5-isopropenyl-2,6-dimethyl-2-cyclohexen-1-one 
• 110222-68-9 (5S,6R)-6-(2-bromo allyl)-6-methyl carvone 

Relevant academic research and scientific papers

A NEW CHIRAL ROUTE TOWARD TERPENOIDS. ANNULATION OF CARVONE TO TRANS- AND CIS-FUSED BICYCLIC SYNTHONS

Starting from carvone, 1 two consecutive alkylations at C-6 followed by an acid-catalyzed cyclization give new bicyclic ketones which are potentially useful chirons for synthesis of terpenes such as drimanes, labdanes and triterpenes.The stereoselectivity

A NEW ANNULATION OF CARVONE TO CHIRAL TRANS AND CIS FUSED BICYCLIC KETONES

Two regiospecific consecutive alkylations of carvone at C6 followed by acid-catalysed cyclisation afford bicyclic ketones which are potential intermediates for the synthesis of several classes of terpenes.Depending on the sequence of alkylation trans fused ketone 7 or mixture of 7 and cis fused 13 may be prepared in only three steps, thus constituting a new type of annulation of carvone.