126786-17-2Relevant academic research and scientific papers
159. Glycosylidene Carbenes - Part 2 - Synthesis of O-Aryl Glycosides
Briner, Karin,Vasella, Andrea
, p. 1764 - 1779 (2007/10/02)
Phenol, 4-methoxyphenol, 4-nitrophenol, methyl orsellinate (1), and 2,6-di(tert-butyl)-4-methylphenol (BHT; 2) have been glycosylated by thermal reaction (20-60 deg C) with various glycosylidene-derived diazirines. 4-Methoxyphenol reacted with the D-gluco
Glycosylidene Carbenes. A New Approach to Glycoside Synthesis. Part 1. Preparation of Glycosylidene-Derived Diaziridines and Diazirines
Briner, Karin,Vasella, Andrea
, p. 1371 - 1382 (2007/10/02)
A new approach towards the synthesis of glycosides based upon a (formal) insertion of glycosylidene carbenes into O-H bonds is presented.The synthesis and characterization of the glycosylidene-derived diazirines 25-28, precursors of glycosylidene carbenes
