126798-96-7Relevant academic research and scientific papers
REACTIVITY OF IMINOPHOSPHORANES TOWARDS SOME SYMMETRICAL DICARBONYL DICHLORIDES : SYNTHESES AND MECHANISMS
Aubert, Thierry,Farnier, Michel,Guilard, Roger
, p. 53 - 60 (2007/10/02)
In situ generated iminophosphoranes 1 react with dicarbonyl dihalides 2a-b and 3a-c to give known or new nitrogen heterocycles.The proposed mechanisms involve elimination of either triphenyl-phosphine oxide or dichlorotriphenylphosphorane depending upon both the iminophosphorane and the dicarbonyl compound.
Condensation of Iminophosphoranes with Dicarbonyl Dihalides: A One-Step Synthesis of New Azepine Derivatives
Aubert, Thierry,Farnier, Michel,Guilard, Roger
, p. 149 - 150 (2007/10/02)
New azepine and 3-benzazepine derivatives 3-6 have been synthesized by condensation of iminophosphoranes with adipoyl chloride and 1,2-benzenediacetyl dichloride, respectively.
