1268266-95-0Relevant articles and documents
Gold-catalyzed stereoselective synthesis of Di- or trisubstituted olefins possessing a 1,4-diene framework via intramolecular allylation of alkynes
Horino, Yoshikazu,Nakashima, Yuichi,Hashimoto, Ken,Kuroda, Shigeyasu
, p. 2879 - 2882 (2011/03/18)
The cationic gold(I)-catalyzed reaction of 1-alkynyl-2-allylsilylbenzenes with water results in intramolecular allylation of the alkynes via 7-exo-dig cyclization to give 1,4-dienes in good yield with excellent stereoselectivities. Georg Thieme Verlag Stu