1268268-37-6

Basic information

• Product Name: benzyl 2-(2-aminonaphthalen-1-yl)-4-methylphenylcarbamate
• Synonyms: benzyl 2-(2-aminonaphthalen-1-yl)-4-methylphenylcarbamate
• CAS NO: 1268268-37-6
• Molecular Weight: 382.462
• Mol File: 1268268-37-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl 2-(2-aminonaphthalen-1-yl)-4-methylphenylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 2-(2-aminonaphthalen-1-yl)-4-methylphenylcarbamate(1268268-37-6)
• EPA Substance Registry System: benzyl 2-(2-aminonaphthalen-1-yl)-4-methylphenylcarbamate(1268268-37-6)

Safety Data

• Hazardous Substances Data: 1268268-37-6(Hazardous Substances Data)

Upstream product

• 1268268-19-4 benzyl 2-(naphthalen-2-yl)-1-p-tolylhydrazinecarboxylate 
• 1197055-07-4 benzyl 1-p-tolylhydrazinecarboxylate 

Relevant articles and documents

Acid-catalyzed [3,3] sigmatropic rearrangement of N-Cbz-diaryl hydrazide for the synthesis of mono-N-Cbz-1,1′-biaryl-2,2′-diamine

N-Cbz-Diaryl hydrazides undergo acid-catalyzed [3,3] sigmatropic rearrangement to afford N-Cbz-1,1′-biaryl-2,2′-diamines. The resultant products can be versatile synthetic platforms for a wide variety of C2- and/or nonsymmetric axially chiral ligands and organocatalysts. N-Cbz-Diaryl hydrazides bearing either a neutral or electron-donating group underwent highly efficient acid-catalyzed [3,3] sigmatropic rearrangement to afford N-Cbz-1,1′-biaryl-2,2′-diamines. The resultant products allow elaboration of various new C2- and/or nonsymmetric axially chiral ligands or organocatalysts.