126833-53-2Relevant articles and documents
A highly active diradical cobalt(iii) catalyst for the cycloisomerization of alkynoic acids
Leconte, Nicolas,Du Moulinet D'Hardemare, Amaury,Philouze, Christian,Thomas, Fabrice
supporting information, p. 8241 - 8244 (2018/07/29)
The first cobalt-catalysed cycloisomerisation of alkynoic acids is reported, thanks to the design of a well-defined diradical cobalt(iii) catalyst, in the absence of any additives. The high efficiency, regioselectivity and chemoselectivity are comparable to those of noble metal-based systems. The unique reactivity might be attributed to second coordination sphere effects.
THE FIELD OF (TRIHALOGENOMETHYL)CARBINOLS. V. SYNTHESIS OF FUNCTIONALLY SUBSTITUTED 3- AND 4-PENTEN-4-OLIDES
Gukasyan, A. O.,Galstyan, L. Kh.,Gyuchov, M. G.,Avetisyan, A. A.
, p. 1548 - 1554 (2007/10/02)
The 1,1-dichloro-2-arylethylene oxides generated from arylz9trichloromethyl)carbinols in the potassium hydroxide-DMFA medium react with the carbanions of malonic and acetoacetic esters, forming diethyl 2,5-diethoxycarbonyl- and 2,5-diacetyl-4-aryl-3oxoadi