1268522-66-2Relevant academic research and scientific papers
Crystal structure of a μ-oxo-bridged dimeric iron(III) complex
Yahsi,Gungor,Kazak,Kara
, p. 1540 - 1544 (2015)
A dimeric [{Fe(5-ClL1)}2(μ-O)], [H2-5-ClL1 = N,N′-bis(5-chloro-2-hydroxybenzylidene)-2-methylpropane-1,2-diamine] tetradentate Schiff-base complex, 1, has been synthesized and its crystal structure has been determined by single crystal X-ray diffraction analysis. Structural analysis of complex 1 shows that the complex is a centrosymmetric dimer. Each of the Fe(III) ions has a five-coordinate geometry and one oxygen atom bridges two Fe(III) ions to form a μ-oxo structure. The geometry around iron atom can be described as a square based pyramid with the FeN2O2 coordination plane and oxo ligand.
