126856-02-8

Basic information

• Product Name: (R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-p-tolylsulfanyl-dodecanoic acid ethyl ester
• CAS NO: 126856-02-8
• Molecular Weight: 480.828
• Mol File: 126856-02-8.mol

Chemical Properties

• CAS DataBase Reference: (R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-p-tolylsulfanyl-dodecanoic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-p-tolylsulfanyl-dodecanoic acid ethyl ester(126856-02-8)
• EPA Substance Registry System: (R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-p-tolylsulfanyl-dodecanoic acid ethyl ester(126856-02-8)

Safety Data

• Hazardous Substances Data: 126856-02-8(Hazardous Substances Data)

Upstream product

• 126855-97-8 tert-Butyl-dimethyl-[(R)-1-((R)-toluene-4-sulfinylmethyl)-nonyloxy]-silane 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 96938-02-2 (R)-1-((R)-Toluene-4-sulfinyl)-decan-2-ol 
• 18295-66-4 1-ethoxy-1-(trimethylsiloxy)ethene 
• 126855-99-0 tert-Butyl-[(R)-1-(chloro-p-tolylsulfanyl-methyl)-nonyloxy]-dimethyl-silane 

Relevant articles and documents

Lewis Acid-Mediated Carbon-Carbon Bond Forming Reaction Using the Pummerer Rearrangement Products from Chiral β-Hydroxy Sulfoxides

The Pummerer rearrangement products, obtained from (RC,RS)-β-hydroxy sulfoxide derivatives, react with silyl enol ethers or a ketene silyl acetal in the presence of ZnBr2 to give the γ-hydroxy-β-tolylthio carbonyl derivatives, which, in turn, are converted to optically pure (E)-γ-hydroxy-α,β-unsaturated carbonyl compounds and 5-substituted 2(5H)-furanones, respectively.