126860-27-3

Upstream product

• 28005-97-2 [PtCl₂(propionitrile)₂] 
• 175871-67-7 (+/-)-2,2'-bis(diphenylphosphino)-1,1'-bibenzimidazole 
• 76144-87-1 (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl 
• 10025-65-7 platinum(II) chloride 

Downstream Products

• 171415-15-9 (C₁₀H₆)2(P(C₆H₅)2)2Pt(OSO₂CF₃)2*H₂O 
• 171415-15-9 [Pt((R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(H₂O)(triflate)](triflate) 
• 162588-41-2 Pt((R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)(I)(3,5-Br₂C₆H₃) 
• 140155-74-4 Pt((R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)(3,5-Br₂C₆H₃)2 
• 162588-40-1 Pt((R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)(η(2)-ethene) 
• 171415-15-9 S(-)-o'-(1,1'-binaphthyl-2,2'-diyl)bis(diphenylphosphane)platinum(II) triflate 
• 177568-56-8 Pt(C₆H₅)2PC₂₀H₁₂P(C₆H₅)2(SO₃CF₃)⁽¹⁺⁾*CF₃SO₃^(1-)=Pt((C₆H₅)2PC₂₀H₁₂P(C₆H₅)2)(SO₃CF₃)2 

Relevant academic research and scientific papers

Combinatorial approach to chiral tris-ligated carbophilic platinum complexes: Application to asymmetric catalysis

A straightforward methodology for the synthesis of libraries of chiral tris-ligated cationic platinum complexes and their in situ evaluation as asymmetric carbophilic catalysts in a model domino hydroarylation/cyclization reaction of a 1,6-enyne was developed. A catalyst-generation process based on a combination of a monodentate and a bidentate phosphorus ligand allowed the formation of 108 chiral complexes. One-pot screening of the stereoinduction obtained with this library in a test domino addition/cyclization reaction validated this approach and stressed the key role played by the monodentate ligand partner in obtaining high enantioselectivities. In the case of two challenging substrate/nucleophile combinations, the combinatorial approach resulted in a significant gain in enantioselectivity.

Effects of the electronic properties of chiral chelating diphosphines in stereoselective Diels-Alder cycloaddition reactions promoted by their transition metals complexes

The Pd(II) and Pt(II) complexes (perchlorates and hexafluoroantimoniates, respectively) of a series of C2 symmetric biheteroaromatic diphosphines differing in their electronic properties at phosphorus have been tested as catalysts in [4 + 2]-cy