1268614-82-9Relevant academic research and scientific papers
A Fluorinated Carbanionic Substituent for Improving Water Solubility and Lipophilicity of Fluorescent Dyes
Yanai, Hikaru,Hoshikawa, Shoki,Moriiwa, Yukiko,Shoji, Atsushi,Yanagida, Akio,Matsumoto, Takashi
, p. 5168 - 5172 (2021)
Installation of a carbanionic substituent, that is strongly stabilized by two (trifluoromethyl)sulfonyl (Tf=SO2CF3) groups, into several fluorescence dyes including boron-dipyrromethenes (BODIPYs), fluoresceins, and aminocoumarins ha
Phenyliodine(III) bis(trifluoroacetate) (PIFA)-promoted synthesis of bodipy dimers displaying unusual redox properties
Rihn, Sandra,Erdem, Mustafa,De Nicola, Antoinette,Retailleau, Pascal,Ziessel, Raymond
supporting information; experimental part, p. 1916 - 1919 (2011/06/24)
Phenyliodine(III) bis(trifluoroacetate) (PIFA) in conjunctionwith a Lewis acid promotes C-C coupling of Bodipy monomers leading to mixtures of various oligomers. when a single position is blockedwith an iodo or phenyl group, formation of the dimer is favored. These dimers display two successive oxidation and two reductionWves separated on average by 260 and 130 mV, respectively, corresponding to each Bodipy subunit.
