1268720-12-2Relevant academic research and scientific papers
Highly efficient organocatalytic kinetic resolution of activated nitroallylic acetates with aldehydes via conjugate addition-elimination
Reddy, Raju Jannapu,Chen, Kwunmin
, p. 1458 - 1461 (2011)
A novel, efficient, and unprecedented organocatalytic kinetic resolution has been developed. For the first time, a variety of nitroallylic acetates 1a-i have been resolved with aldehydes in the presence of 2 (2.5 mol %) via conjugate addition-elimination.
Kinetic resolution of activated nitroallylic acetates with aldehydes and ketones through a conjugate addition-elimination SN2′ process
Jannapu Reddy, Raju,Lee, Pei-Hsun,Magar, Dhananjay R.,Chen, Jung-Hsuan,Chen, Kwunmin
experimental part, p. 353 - 365 (2012/02/04)
A unique organocatalytic kinetic resolution (KR) of nitroallylic acetates has been developed. A variety of racemic nitroallylic acetates (1a-n) were resolved with chiral enamines formed in situ from the reaction of aldehydes and ketones with organocatalys
