126875-56-7Relevant articles and documents
Reactions of Trialkylsilyl Trifluoromethanesulfonates, IX. - Electrophilic Silylation of Electron-Rich Alkenes
Schulz, Dieter,Simchen, Gerhard
, p. 745 - 750 (2007/10/02)
Ketene O,O-, O,S-, and O,N-acetals 1, 7, and 9 are converted into the C-silylated derivatives 4, 8, and 11, respectively, by reaction with trimethylsilyl triflate (2a)/tertiary amine or sodium hydride.The ambident character of the ketene O,O-acetals 1 in