126889-49-4Relevant academic research and scientific papers
The selective distinction of diethylisopropylsilyl ether in hydrogenolysis
Toshima, Kazunobu,Yanagawa, Koji,Mukaiyama, Satsuki,Tatsuta, Kuniaki
, p. 6697 - 6698 (1990)
The diethylisopropylsilyl ether was distinguished from t-butyldimethysilyl, t-butyldiphenylsilyl and benzyl ethers with high selectivity in hydrogenolysis by use of Pd(OH)2 as a catalyst.
The diethylisopropylsilyl group: A new protecting group for alcohols
Toshima,Mukaiyama,Kinoshita,Tatsuta
, p. 6413 - 6416 (2007/10/02)
The diethylisopropylsilyl (DEIPS) group which is a new protective group for alcohols has been first characterized. DEIPS group can be distinguished from t-butyldimethylsilyl, triethylsilyl, tetrahydropyranyl groups and 2-deoxy glycoside with high selectivity in removing under mild acidic condition, although DEIPS group has high stability to many useful organic synthetic reaction conditions.
