126934-49-4Relevant academic research and scientific papers
Facile epoxidation of α, β-unsaturated ketones with urea-2,2-dihydroperoxypropane as a new oxidant
Khosravi, Kaveh,Naserifar, Shirin
, p. 323 - 328 (2017)
Abstract: Various aromatic α, β-unsaturated ketones were successfully transformed into their corresponding epoxides using urea-2,2-dihydroperoxypropane as the oxygen source for the first time. The reactions were carried out under mild alkaline conditions at room temperature in high yields and short reaction times. Graphical Abstract: [Figure not available: see fulltext.]
Metal-Free and Efficient Epoxidation of α,β-Unsaturated Ketones with 1,1,2,2-Tetrahydroperoxy-1,2-Diphenylethane as a Powerful Solid Oxidant
Khosravi, Kaveh,Naserifar, Shirin,Mahmoudi, Boshra
, p. 683 - 689 (2017/06/19)
1,1,2,2-Tetrahydroperoxy-1,2-diphenylethane was used for the efficient and metal-free epoxidation of various α,β-unsaturated ketones, carried out under mild alkaline conditions at room temperature.
Regioselective opening of chalcone epoxides with nitrogen heterocycles using indium(III) chloride as an efficient catalyst
Konduru, Naveen Kumar,Ahmed, Naseem
supporting information, p. 2008 - 2018 (2013/06/27)
Indium(III) chloride catalyzes regioselective ring opening of chalcone epoxides with nitrogen heterocycles such as indole, 2-methyl indole, and pyrrole under mild conditions at room temperature to afford 1,3-diaryl-2-hydroxy-3-(1H- 3-indolyl/2-pyrrolyl)propan-1-ones in good yields (60-88%) within 20-50 min. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications to view the free supplemental file.
