1269772-87-3Relevant academic research and scientific papers
Iron-catalysed Markovnikov hydrothiolation of styrenes
Cabrero-Antonino, Jose R.,Leyva-Perez, Antonio,Corma, Avelino
supporting information; experimental part, p. 678 - 687 (2012/04/18)
The bis(triflimide)iron(III) salt catalyzes the hydrothiolation of styrenes in a Markovnikov fashion with good selectivities and high yields. After isolation, different benzylic thioethers are obtained. This iron(III) catalyst is unique in terms of regioselectivity and represents a sustainable and economic alternative to those processes based on stoichiometric reagents. Copyright
Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols
Ding, Qiuping,Cao, Banpeng,Yuan, Jianjun,Liu, Xianjin,Peng, Yiyuan
supporting information; experimental part, p. 748 - 751 (2011/03/22)
A metal-free procedure for the synthesis of thioethers is described via the base-promoted reductive coupling of tosylhydrazones with thiols through an insertion of a carbene into the S-H bond.
