126986-28-5Relevant articles and documents
Gold(I)/copper(II)-cocatalyzed tandem cyclization/semipinacol reaction: Construction of 6-Aza/Oxa-Spiro[4.5]decane skeletons and formal synthesis of (±)-halichlorine
Zhu, Dao-Yong,Zhang, Zhen,Mou, Xue-Qing,Tu, Yong-Qiang,Zhang, Fu-Min,Peng, Jin-Bao,Wang, Shao-Hua,Zhang, Shu-Yu
, p. 747 - 752 (2015)
A simple and efficient strategy for the construction of 6-aza/oxa-spiro[4.5]decane skeletons under the cocatalysis of gold(I)/copper(II) was developed, and its potential utility was demonstrated by a formal synthesis of the biologically active marine alkaloid (±)-halichlorine.
Selective mono-acylation of meso- and C2-symmetric 1,3- and 1,4-diols
Clarke, Paul A.
, p. 4761 - 4763 (2007/10/03)
The direct one-pot mono-acylation of meso and C2-symmetric 1,3- and 1,4-diols has been achieved using carboxylic acid anhydrides and catalytic amounts of cerium trichloride.
Enzyme catalyzed monohydrolysis of 2-aryl-1 3-propanediol diacetates. A study of structural effects of the aryl moiety on the enantioselectivity
Guanti, Giuseppe,Narisano, Enrica,Podgorski, Tadeusz,Thea, Sergio,Williams, Andrew
, p. 7081 - 7092 (2007/10/02)
PPL catalyzed monohydrolysis of 2-aryl substituted 13-propanediol diacetates afforded the corresponding monoacetates in acceptable to fair chemical and optical yields. Electronic effects in the aromatic ring were examined. Elaboration of some 2-arylpropanediol monoacetates to optically active 2-arylpropanols and propanoic acids was performed.
