127015-49-0Relevant academic research and scientific papers
oxotitanium. A Chemoselective and Efficient Catalyst for Aldol-type Reaction of Ketene Silyl Acetals with Aldehydes
Hara, Ryuichiro,Mukaiyama, Teruaki
, p. 1909 - 1912 (1989)
In the presence of catalytic amount of oxotitanium, ketene silyl acetals smoothly react with aldehydes to afford the corresponding β-hydroxy carboxylic esters in good yields under mild conditions.According to this procedure, a
Reversal Phenomena of the Preferential Activation of Aldehydes to the Corresponding Acetals under Non-Basic Conditions. The Chemoselective Aldol Reaction of Aldehydes with t-Butyldimethylsilyl Enol Ethers Using TBSCl-InCl3 as a Catalyst
Mukaiyama, Teruaki,Ohno, Takashi,Han, Jeong Sik,Kobayashi, Shu
, p. 949 - 952 (2007/10/02)
In the presence of a catalytic amount of t-butyldimethylsilyl chloride (TBSCl) and indium(III) chloride (InCl3), aldehydes smoothly react with t-butyldimethylsilyl enol ethers to afford the corresponding aldol adducts in good yields whereas acetals do not
