127016-91-5Relevant academic research and scientific papers
HIGHLY DIASTEREOSELECTIVE DIELS-ALDER REACTION OF OPTICALLY ACTIVE 2-p-TOLYLSULPHINYL-2-CYCLOALKENONES WITH CYCLOPENTADIENE
Alonso, I.,Carretero, J. C.,Ruano, J. L. Garcia
, p. 3853 - 3856 (2007/10/02)
The Diels-Alder reaction of (S)-2-p-tolylsulphinyl-2-cyclopentenone (and 2-cyclohexenone) with cyclopentadiene, catalized by AlCl3 and AlEtCl2, occurs at room temperature with complete facial diastereoselectivity, but with moderate endo-exo selectivity.
