127032-78-4

Basic information

• Product Name: <2-(ethoxycarbonyl)-2-<(2-tetrahydropyranyloxy)imino>ethyl>triphenylphosphonium bromide
• Synonyms: <2-(ethoxycarbonyl)-2-<(2-tetrahydropyranyloxy)imino>ethyl>triphenylphosphonium bromide
• CAS NO: 127032-78-4
• Molecular Weight: 556.436
• Mol File: 127032-78-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: <2-(ethoxycarbonyl)-2-<(2-tetrahydropyranyloxy)imino>ethyl>triphenylphosphonium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: <2-(ethoxycarbonyl)-2-<(2-tetrahydropyranyloxy)imino>ethyl>triphenylphosphonium bromide(127032-78-4)
• EPA Substance Registry System: <2-(ethoxycarbonyl)-2-<(2-tetrahydropyranyloxy)imino>ethyl>triphenylphosphonium bromide(127032-78-4)

Safety Data

• Hazardous Substances Data: 127032-78-4(Hazardous Substances Data)

Upstream product

• 134288-26-9 3-bromo-2-hydroxyimino-propionic acid ethyl ester 
• 70-23-5 ethyl Bromopyruvate 
• 110-87-2 3,4-dihydro-2H-pyran 
• 127033-05-0 ethyl 2-<(2-tetrahydropyranyloxy)imino>-3-bromopropanoate 
• 603-35-0 triphenylphosphine 

Downstream Products

• 127032-98-8 (2R^*,3S^*,4S^*)-2-ethoxy-6-(ethoxycarbonyl)-3-methyl-4-phenyl-1-(phenylsulfonyl)-1,2,3,4-tetrahydropyridine 
• 127033-03-8 (2R^*,4R^*)-6-(ethoxycarbonyl)-2,4-diphenyl-1-(phenylsulfonyl)-1,2,3,4-tetrahydropyridine 
• 127032-99-9 (2R^*,3R^*,4S^*)-2-(benzyloxy)-6-(ethoxycarbonyl)-3-methyl-4-phenyl-1-(phenylsulfonyl)-1,2,3,4-tetrahydropyridine 
• 127063-55-2 (2R^*,4R^*)-6-(ethoxycarbonyl)-2-(4'-methoxyphenyl)-4-(phenyl)-1-(phenylsulfonyl)-1,2,3,4-tetrahydropyridine 
• 127032-97-7 (2R^*,4S^*)-2-(benzyloxy)-6-(ethoxycarbonyl)-4-phenyl-1-(phenylsulfonyl)-1,2,3,4-tetrahydropyridine 
• 127033-01-6 (2R^*,3R^*,4R^*)-3-acetoxy-2-(benzyloxy)-6-(ethoxycarbonyl)-4-phenyl-1-(phenylsulfonyl)-1,2,3,4-tetrahydropyridine 
• 127033-01-6 (2R^*,3S^*,4R^*)-3-acetoxy-2-(benzyloxy)-6-(ethoxycarbonyl)-4-phenyl-1-(phenylsulfonyl)-1,2,3,4-tetrahydropyridine 
• 127032-92-2 (2R^*,4S^*)-2-ethoxy-6-(ethoxycarbonyl)-4-n-hexyl-1-(phenylsulfonyl)-1,2,3,4-tetrahydropyridine 
• 127033-01-6 (4R,5S,6R)-5-Acetoxy-1-benzenesulfonyl-6-benzyloxy-4-phenyl-1,4,5,6-tetrahydro-pyridine-2-carboxylic acid ethyl ester 
• 127033-01-6 (4R,5R,6R)-5-Acetoxy-1-benzenesulfonyl-6-benzyloxy-4-phenyl-1,4,5,6-tetrahydro-pyridine-2-carboxylic acid ethyl ester 
• 127032-97-7 (4R,6R)-1-Benzenesulfonyl-6-benzyloxy-4-phenyl-1,4,5,6-tetrahydro-pyridine-2-carboxylic acid ethyl ester 
• 127063-55-2 (4S,6R)-1-Benzenesulfonyl-6-(4-methoxy-phenyl)-4-phenyl-1,4,5,6-tetrahydro-pyridine-2-carboxylic acid ethyl ester 
• 127032-99-9 (4S,5R,6R)-1-Benzenesulfonyl-6-benzyloxy-5-methyl-4-phenyl-1,4,5,6-tetrahydro-pyridine-2-carboxylic acid ethyl ester 
• 127033-03-8 (4S,6R)-1-Benzenesulfonyl-4,6-diphenyl-1,4,5,6-tetrahydro-pyridine-2-carboxylic acid ethyl ester 

Relevant articles and documents

Room Temperature, Endo-Specific 1-Aza-1,3-butadiene Diels-Alder Reactions: Acceleration of the LUMOdiene-Controlled Cycloaddition Reactions through Noncomplementary Azadiene Substitution

A preparation of N-sulfonyl-2-(ethoxycarbonyl)-1-aza-1,3-butadienes 5-6 is described and is based on the use of the stabilized Wittig reagent 1 and implementation of a subsequent room temperature, in situ homolytic oxime O-sulfinyl to N-sulfonyl rearrange