127075-50-7

Upstream product

• 85657-09-6 (S)-(+)-2-Pyrrolidinmethanthiol 
• 23356-96-9 (S)-1-Pyrrolidin-2-yl-methanol 
• 127075-44-9 (S)-2-Imino-1-aza-3-thiabicyclo<3.3.0>octan-hydrobromid 
• 51368-34-4 (S)-(+)-2-(bromomethyl)pyrrolidine hydrobromide 
• 85657-11-0 (S)-(-)-1-Aza-7-thiabicyclo<3.2.0>heptan-7,7-dioxid 
• 100-46-9 benzylamine 

Relevant academic research and scientific papers

Bicyclic β-sultams: Synthesis from monocyclic β-aminothiols and some properties

The cyclamine methanethiols 7 are prepared from the corresponding alcohols 3 and oxidatively transformed by treatment with chlorine into the cyclic substituted taurinechlorides 8. Upon treatment with bases, 8 is cyclized yielding the bicyclic β-sultams 9. Some spectroscopic properties and the solvolysis of 9 are briefly discussed.