1271169-73-3

Basic information

• Product Name: C₈H₁₁F₆NO₄S₂
• Synonyms: C₈H₁₁F₆NO₄S₂
• CAS NO: 1271169-73-3
• Molecular Weight: 363.302
• Mol File: 1271169-73-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₈H₁₁F₆NO₄S₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₈H₁₁F₆NO₄S₂(1271169-73-3)
• EPA Substance Registry System: C₈H₁₁F₆NO₄S₂(1271169-73-3)

Safety Data

• Hazardous Substances Data: 1271169-73-3(Hazardous Substances Data)

Upstream product

• 90076-67-8 potassium bis(trifluoromethylsulfonyl)imide 

Relevant articles and documents

Weakly nucleophilic conjugate bases of superacids as powerful nucleophiles in vinylic bimolecular nucleophilic substitutions of simple β- alkylvinyl(aryl)-λ3-bromanes

We report herein, for the first time, the stereoselective synthesis of simple (E)-β-alkylvinyl(aryl)-λ3-bromanes via a boron-λ3-bromane exchange reaction and their unique bimolecular nucleophilic substitutions at the vinylic ipso carbon atom under mild conditions. Interestingly, even weakly nucleophilic anions such as conjugate bases of superacids (HBF4, TfOH, Tf2CH 2, Tf3CH, Tf2NH, etc.) function as nucleophiles toward the vinyl-λ3-bromanes. For instance, the vinylic SN2 reaction of (E)-vinyl-λ3-bromanes with potassium bis(triflyl)methanide stereoselectively produced (Z)-vinyloxy oxosulfonium ylides with exclusive inversion of configuration via oxygen attack, while that with potassium bis(triflyl)imide afforded predominantly (Z)-vinyloxysulfoximines. In marked contrast, (E)-β-alkylvinyl- λ3-iodanes do not undergo the vinylic SN2 reaction with these conjugate bases of superacids. The differences between the nucleofugalities of aryl-λ3-iodanyl and aryl- λ3-bromanyl groups (the latter being greater) probably play a pivotal role in these unique reactions.