1271193-75-9Relevant academic research and scientific papers
Strain-promoted azide-alkyne cycloadditions of benzocyclononynes
Tummatorn, Jumreang,Batsomboon, Paratchata,Clark, Ronald J.,Alabugin, Igor V.,Dudley, Gregory B.
, p. 2093 - 2097 (2012/05/19)
Preliminary studies related to the design and development of new cycloalkyne reagents for metal-free click coupling are reported. Cyclononynes are more stable than cyclooctynes, and the robust benzocyclononyne platform offers spontaneous reactivity toward
Generation of medium-ring cycloalkynes by ring expansion of vinylogous acyl triflates
Tummatorn, Jumreang,Dudley, Gregory B.
, p. 1572 - 1575 (2011/04/26)
Reductive cyclization of aryl and vinyl iodides tethered to vinylogous acyl triflates (VATs) induces a ring-expanding fragmentation to provide cyclic alkynyl ketones, including strained nine-membered cycloalkynes, in fair to excellent yield. The tandem cy
