127130-45-4

Basic information

• Product Name: (2S,5R)-5-methyl-4-(phenylselenyl)-3-heptyl-2-(methoxycarbonyl)-2,5-dihydrofuran
• CAS NO: 127130-45-4
• Molecular Weight: 395.401
• Mol File: 127130-45-4.mol

Chemical Properties

• CAS DataBase Reference: (2S,5R)-5-methyl-4-(phenylselenyl)-3-heptyl-2-(methoxycarbonyl)-2,5-dihydrofuran(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,5R)-5-methyl-4-(phenylselenyl)-3-heptyl-2-(methoxycarbonyl)-2,5-dihydrofuran(127130-45-4)
• EPA Substance Registry System: (2S,5R)-5-methyl-4-(phenylselenyl)-3-heptyl-2-(methoxycarbonyl)-2,5-dihydrofuran(127130-45-4)

Safety Data

• Hazardous Substances Data: 127130-45-4(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 127130-40-9 methyl (2S,4R)-2-hydroxy-3-heptyl-3,4-hexadienecarboxylate 

Relevant articles and documents

Wittig Rearrangement of Nonracemic Propargyloxyacetic Acids and Esters. Synthesis of Optically Active 2,5-Dihydrofurans

Optically active propargyloxyacetic acids 4, available in ca. 90percent ee through reduction of alkynones 2 with Chirald-LiAlH4 followed by alkylation with chloroacetic acid, undergo highly stereoselective rearrangement upon treatment with LDA in TH

Synthesis of Enantioenriched α-Hydroxy-α-allenylacetic Acids by Wittig Rearrangement of (Propargyloxy)acetates

Optically active (R)-(propargyloxy)acetic esters 5, available in ca. 90 percent ee through reduction of alkynones 2 with Chirald-LiAlH4 followed by alkylation with chloroacetic acid and esterification with CH2N2, undergo highly stereoselective rearr