127183-00-0Relevant academic research and scientific papers
Thioaldehyde S-Oxide (Monosubstituted Sulfines) from Thioacylsilane S-Oxides. Synthesis and Fluorine- and Acid-Induced Z/E Isomerization. 2
Barbaro, G.,Battaglia, A.,Giorgianni, P.,Bonini, B. F.,Maccagnani, G.,Zani, P.
, p. 3744 - 3748 (2007/10/02)
Aromatic and aliphatic, not enethiolizable, thioaldehyde S-oxides (monosubstituted sulfines) are obtained from stereospecific fluorodesilylation of the corresponding thioacylsilane S-oxides with retention of configuration.A detailed investigation on the mechanism of the desilylation, as well as of the acid and fluoride ion induced Z/E interconversion has been performed.
