1272005-91-0Relevant academic research and scientific papers
Metal-silicon triple bonds: Nucleophilic addition and redox reactions of the silylidyne complex [Cp(CO)2MoξSi-R]
Filippou, Alexander C.,Chernov, Oleg,Schnakenburg, Gregor
, p. 1122 - 1126 (2011/04/15)
As a silicon analogue of metal alkylidyne complexes, the title compound offers new perspectives in organosilicon chemistry. The high synthetic potential of 1 is demonstrated by a series of reactions that provide access to the first anionic silylidene complexes and dianionic silyl complexes (see scheme; Nu= Cl, N3, CH3; R=C6H3-2,6-Trip 2).
