127220-18-2Relevant articles and documents
Reaction of gem-dibromocyclopropanes or iodobenzofuran with trialkylmanganate
Kakiya, Hirotada,Inoue, Rie,Shinokubo, Hiroshi,Oshima, Koichiro
, p. 2131 - 2137 (2007/10/03)
Treatment of gem-dibromocyclopropanes with trialkylmanganate, derived from manganese(II) chloride and three equivalents of Grignard reagent or alkyllithium, followed by an addition of electrophiles provided dialkylated cyclopropanes in good yields. It was
Generation and alkylation reaction of lithium 1-halocyclopropylzincate
Harada,Hattori,Katsuhira,Oku
, p. 6035 - 6038 (2007/10/02)
Lithium dialkyl (1-halocyclopropyl) zincates which are generated from 1, 1-dibromocyclopropanes undergo intramolecular alkylation to give 1-alkylcyclopropanes stereoselectively.
