127220-24-0Relevant academic research and scientific papers
Stereoselective Carbon-Carbon Bond-Forming Reaction of 1,1-Dibromocyclopropanes via 1-Halocyclopropylzincates
Harada, Toshiro,Katsuhira, Takeshi,Hattori, Kazuhiro,Oku, Akira
, p. 2958 - 2965 (2007/10/02)
Lithium trialkylzincates react efficiently with 1,1-dibromocyclopropanes 5 to give the corresponding alkylation products 7 nonstereoselectively.The reaction proceeds through a 1,2-alkyl migration of the intermediately formed zincate carbenoid 3 in an inve
Generation and alkylation reaction of lithium 1-halocyclopropylzincate
Harada,Hattori,Katsuhira,Oku
, p. 6035 - 6038 (2007/10/02)
Lithium dialkyl (1-halocyclopropyl) zincates which are generated from 1, 1-dibromocyclopropanes undergo intramolecular alkylation to give 1-alkylcyclopropanes stereoselectively.
