127223-15-8

Basic information

• Product Name: Cyclopropanol, 1-[2-(phenylthio)ethyl]-
• CAS NO: 127223-15-8
• Molecular Formula: C11H14OS
• Molecular Weight: 194.298
• Mol File: 127223-15-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclopropanol, 1-[2-(phenylthio)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanol, 1-[2-(phenylthio)ethyl]-(127223-15-8)
• EPA Substance Registry System: Cyclopropanol, 1-[2-(phenylthio)ethyl]-(127223-15-8)

Safety Data

• Hazardous Substances Data: 127223-15-8(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 17277-58-6 methyl (phenylsulfanyl)acetate 

Relevant articles and documents

Reactions of Carbonyl Compounds with Benzyl Chloromethyl Ether of Diiodomethane in the Presence of Samarium(II) Iodide or Metallic Samarium. New Routes to 1,2-Diols, Iodohydrins and Cyclopropanols

Carbonyl compounds react with benzyl chloromethyl ether in the presence of samarium(II) iodide to afford the corresponding addition products which, when subsequently hydrogenolysed, yield 1,2-diols.Simple aldehydes and ketones react with diiodomethane in the presence of samarium metal to give iodohydrins in good yields.Under similar reaction conditions, α-halogeno substituted ketones and aromatic 1,4-diketones are converted into cyclopropanols.These cyclopropanations have been shown to rpoceed through the initial generation of samarium enolates, followed by the Simmons-Smith type reaction.A novel transformation of esters to cyclopropanols via tandem one-carbon homologation is also described.