127236-28-6

Basic information

• Product Name: (4S,4aR,7aR)-4,6-Diphenyl-2-[(E)-phenylimino]-tetrahydro-pyrrolo[3,4-e][1,3]thiazine-5,7-dione
• Synonyms: (4S,4aR,7aR)-4,6-Diphenyl-2-[(E)-phenylimino]-tetrahydro-pyrrolo[3,4-e][1,3]thiazine-5,7-dione
• CAS NO: 127236-28-6
• Molecular Weight: 413.5
• Mol File: 127236-28-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4S,4aR,7aR)-4,6-Diphenyl-2-[(E)-phenylimino]-tetrahydro-pyrrolo[3,4-e][1,3]thiazine-5,7-dione(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,4aR,7aR)-4,6-Diphenyl-2-[(E)-phenylimino]-tetrahydro-pyrrolo[3,4-e][1,3]thiazine-5,7-dione(127236-28-6)
• EPA Substance Registry System: (4S,4aR,7aR)-4,6-Diphenyl-2-[(E)-phenylimino]-tetrahydro-pyrrolo[3,4-e][1,3]thiazine-5,7-dione(127236-28-6)

Safety Data

• Hazardous Substances Data: 127236-28-6(Hazardous Substances Data)

Upstream product

• 103-72-0 phenyl isothiocyanate 
• 17599-61-0 N-benzylidene-1,1,1-trimethylsilanamine 
• 941-69-5 N-phenyl-maleimide 
• 121910-68-7 C₁₇H₂₀N₂SSi 

Relevant articles and documents

An efficient, one-pot synthesis of 1,3-thiazines and 1,2,3,5-thiatriazines from N-(trimethylsilyl)imines via [4 + 2] cycloaddition of 1-thia-3-azadienes

The [4 + 2] cycloaddition reaction of 2-amino-1-thia-3-azabutadienes 2, formed in situ from N-(trimethylsilyl)imines 1 and phenyl isothiocyanate, towards electron-poor dienophiles is described. The process is applied to a number of carbo- and heterodienophiles, allowing the regioselective formation of the cycloadducts 3-7 with complete endo-stereoselectivity.