127239-26-3

Upstream product

• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 53929-49-0 Acetic acid (1R,2R,3S,4R)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5,5-bis-ethylsulfanyl-pentyl ester 

Downstream Products

• 127239-27-4 Acetic acid (E)-(1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-6-nitro-oct-5-enyl ester 
• 127239-27-4 Acetic acid (Z)-(1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-6-nitro-oct-5-enyl ester 
• 127263-08-5 Acetic acid (1R,2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-5-hydroxy-6-nitro-octyl ester 

Relevant academic research and scientific papers

VO(acac)2/H2O2/NaI: A mild and efficient combination for the cleavage of dithioacetal derivatives of sugars

A wide variety of dithioacetal derivatives of sugars can be cleaved easily into the corresponding open-chain aldehydo sugars using an efficient combination of VO(acac)2/H2O2/NaI at 0-5 °C. Some of the salient features of this protocol are mild reaction conditions, good yields, short reaction times, easy work-up procedures, and non-involvement of toxic chemicals.

SILYL NITRONATES IN CARBOHYDRATE CHEMISTRY: CHAIN-EXTENSION REACTIONS

Seebach's silyl nitronate nitroaldol methodology provides a highly efficient variation of the Henry reaction for chain-extension of aldehydo-sugars to higher nitro sugars under extremely mild conditions.