127244-73-9

Upstream product

• 90503-12-1 methyl 4,6-O-benzylidene-3-deoxy-3-iodo-α-D-glucopyranoside 
• 127244-71-7 methyl 2-O-benzoyl-4,6-O-benzylidene-3-deoxy-3-iodo-α-D-glucopyranoside 
• 3150-15-0 methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside 
• 127244-72-8 methyl (3S)-<3-(2)H>-2-O-benzoyl-4,6-O-benzylidene-3-deoxy-α-D-ribo-hexopyranoside 

Downstream Products

• 127218-12-6 methyl (3S)-<3-(2)H>-2,4-di-O-benzoyl-3,6-dideoxy-α-D-ribo-hexopyranoside 

Relevant academic research and scientific papers

Synthesis of stereospecifically labeled 3,6-dideoxyhexoses.

Preparations of ascarylose (3,6-dideoxy-L-arabino-hexose), abequose (3,6-dideoxy-D-xylo-hexose), and paratose (3,6-dideoxy-D-ribo-hexose) with stereospecific deuterium labeling at C-3 are discussed. The methods used to synthesize these sugars, such as the

SYNTHESIS OF STEREOSPECIFICALLY LABELLED CARBOHYDRATES III1,2: PREPARATION OF (3S)- AND (3R)-3-2H1PARATOSE

Two synthetic pathways producing methyl 3,6-dideoxy-α-D-ribo-hexose (methyl paratose) labeled stereospecifically with deuterium at the 3S (1) and 3R (2) position, respectively, are described.