127248-36-6Relevant academic research and scientific papers
Organometallic derivatives of diphosphinoamines, X2PN(R)PX2. Reactions with carbonyl derivatives of group 6 metals and iron pentacarbonyl. The crystal structures of and iPrN(PPh2)2>
Balakrishna, M. S.,Prakasha, T. K.,Krishnamurthy, S. S.,Siriwardane, U.,Hosmane, N. S.
, p. 203 - 216 (2007/10/02)
The diphosphinoamines X2PN(R)PX2 (L) (R = Me or Ph, X = OCH2CF3 or OPh; R = Ph, X = OC6H4Br-p; R = iPr, X = Ph) react with group 6 metal carbonyl derivatives to yield the cis-chelate complexes .The structures of cis- (3d) and cis-iPrN(PPh2)2> (4f) have been established by single crystal X-ray diffraction studies.Reactions with iron pentacarbonyl yield complexes in which a chelating or a bridged-bidentate mode of coordination of the ligands is observed.
