127255-37-2

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 127255-36-1 (1S,3S,5R)-methyl 3-<<(tert-butyldimethylsilyl)oxy>methyl>-4,4,5-trimethylcyclopentanecarboxylate 
• 127255-35-0 (1S,3S,5R)-methyl 3-(hydroxymethyl)-4,4,5-trimethylcyclopentanecarboxylate 
• 307306-66-7 (1S,3S,5R)-3-(carbomethoxy)-4,4,5-trimethylcyclopentanecarboxylic acid 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 127308-32-1 methyl phenylcamphorate 
• 127255-34-9 (1S,3S,5R)-3-(hydroxymethyl)-4,4,5-trimethylcyclopentanecarboxylic acid 

Relevant academic research and scientific papers

Defense Mechanisms of Arthropods. 84. Synthesis of (-)-α-Necrodol and (-)-β-Necrodol: Novel Cyclopentanoid Terpenes from a Carrion Beetle

Syntheses of (-)-α-necrodol (1) and (-)-β-necrodol (2) from (+)-phenylcamphoric acid (7a) are described.In addition, several related compounds, (+)-epi-α-necxrodol (3), (+)-epi-β-necrodol (4), and (+)-γ-necrodol (5), have been prepared.The absolute configuration of natural α-necrodol has been established as 3R,5R by comparison of its (+)-α-methoxy-α-(trifluoromethyl)phenylacetyl ester with the ester derived from synthetic 1.