127266-48-2Relevant academic research and scientific papers
Synthesis of stereodefined β,γ-unsaturated ketones via hydroboration of 1-bromo-3-en-1-ynes
Shoup,Zweifel
, p. 2937 - 2944 (1993)
Sequential hydroboration-oxidation of (E)- and (Z)-1-bromoenynes provides convenient access to (E)- and (Z)-β,γ-unsaturated ketones, respectively.
DIRECTIVE EFFECTS IN HYDROBORATIONS OF 1-(TRIALKYLSILYL)-1,3-DIYNES. SYNTHESES OF (Z)-ENYNES AND α-KETOACETYLENES
Stracker, Elaine C.,Leong, William,Miller, Joseph A.,Shoup, Timothy M.,Zweifel, George
, p. 6487 - 6490 (2007/10/02)
Chemo- and regioselective hydroborations of 1-(dimethylthexylsilyl)-1,3-diynes with dicyclohexylborane or with furnishes organoboranes which afford on protonation (Z)-enynes and on oxidation alkynyl ketones.
