127295-89-0Relevant academic research and scientific papers
Novel Skeletal Rearrangement Reaction of Tetrasilanes with Aryl Isocyanides
Ito, Yoshihiko,Suginome, Michinori,Murakami, Masahiro,Shiro, Motoo
, p. 1494 - 1495 (1989)
A novel skeletal rearrangement of tetrasilanes in the palladium catalysed reaction with aryl isocyanides gives 3,3-disilyl-2,4-disila-1-azacyclobutane derivatives, the structure of one example of which has been determined by X-ray crystallography.
Palladium-catalyzed insertion of isocyanides into the silicon-silicon linkages of oligosilanes
Ito, Yoshihiko,Suginome, Michinori,Matsuura, Takaharu,Murakami, Masahiro
, p. 8899 - 8908 (2007/10/02)
Full details of a study on the reactions of oligosilanes with isocyanides promoted by a palladium catalyst are described. Heating a mixture of oligosilanes and excess 2,6-disubstituted aryl isocyanide in the presence of palladium(II) acetate led to the co
