127348-36-1

Basic information

• Product Name: Trisilane, 2-chloro-1,1,1,3,3,3-hexamethyl-2-phenyl-
• CAS NO: 127348-36-1
• Molecular Formula: C12H23ClSi3
• Molecular Weight: 287.024
• Mol File: 127348-36-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Trisilane, 2-chloro-1,1,1,3,3,3-hexamethyl-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Trisilane, 2-chloro-1,1,1,3,3,3-hexamethyl-2-phenyl-(127348-36-1)
• EPA Substance Registry System: Trisilane, 2-chloro-1,1,1,3,3,3-hexamethyl-2-phenyl-(127348-36-1)

Safety Data

• Hazardous Substances Data: 127348-36-1(Hazardous Substances Data)

Upstream product

• 4235-65-8 tris(trimethylsilyl)phenylsilane 
• 98-13-5 Phenyltrichlorosilane 
• 136839-76-4 C₁₃H₂₃F₃O₃SSi₃ 
• 18549-83-2 1,1,1,3,3,3-hexamethyl-2,2-diphenyltrisilane 
• 56-23-5 tetrachloromethane 

Downstream Products

• 118714-41-3 1,1,1,4,4,4-hexamethyl-2,3-diphenyl-2,3-bis(trimethylsilyl)-n-tetrasilan 
• 1266607-48-0 P₇[SiPh(SiMe₃)2]3 
• 1095281-36-9 fluorobis(trimethylsilyl)phenylsilane 
• 132384-99-7 1,3-diphenyl-2--1,4-bis(trimethylsilyl)-1-silacyclobut-3-ene 
• 132412-33-0 1,3,4-triphenyl-1,2,5-tris(trimethylsilyl)silole 
• 70057-32-8 1-(trimethylsilylethynyl)-1,1-diphenyl-2,2,2-trimethyldisilane 
• 209621-79-4 pentakis(trimethylsilyl)phenyldisilane 
• 129856-11-7 2-methoxy-2-phenylhexamethyltrisilane 

Relevant articles and documents

Photochemical functionalizations of C60 with phenylpolysilanes

Photolyses of tert-butyl substituted disilanes 1a-1c, and 1i with C60 result in the formation of 1,16-adduct 2 through silyl radical addition to fullerene. The unusual products, 3, 5, 6 and 7 where the silyl and phenyl groups attached on 1,2-positions of fullerene are also obtained from the reaction of 1d-g and 4. The structures of all these compounds were determined by one- and two-dimensional NMR techniques.

Reaction of phenyl(trimethylsilyl)silylene with chloromethanes; Insertion into C-Cl bond and abstraction of chlorine and HCl

Photolysis of tris(trimethylsilyl)phenylsilane in chloromethanes, ClnCX(4-n), (n = 1-4, X = H, alkyl, and Cl) produced phenyl(trimethylsilyl)silylene as a major intermediate, which afforded three types of products: 1,1-dichloro-1-phenyltrimethyldisilane via abstraction of two chlorine atoms, 1-alkyl-1-chloro-1-phenyltrimethyl-disilane via insertion into the C-Cl bond, and 1-chloro-1-phenyl-2,2,2-trimethyldisilane via abstraction of HCl.Possible reaction mechanisms for the formation of these products were discussed based on initial formation of an 1,2-zwitterionic intermediate.A small amount of a radical-reaction product, 2-chloro-2-phenyl-hexamethyltrisilane, and a product considered to be a cyclohexadienyl derivative were detected in all cases as minor products.