1273503-96-0

Upstream product

• 291527-20-3 ethyl (2-(tributylstannyl)allyl) carbonate 
• 1273503-15-3 (S)-2-(2,2,2-trifluoroacetamido)-N-[2-(3,4-dihydroquinolin-1(2H)-yl)-2-oxoethyl]-3-phenylpropanamide 

Downstream Products

• 1273504-02-1 (2S)-2-(2,2,2-trifluoroacetamido)-N-[(R)-1-(3,4-dihydroquinolin-1(2H)-yl)-4-methylene-1,5-dioxo-5-phenylpentan-2-yl]-3-phenylpropanamide 
• 1273503-99-3 (2S)-2-(2,2,2-trifluoroacetamido)-N-[(R)-4-benzyl-1-(3,4-dihydroquinolin-1(2H)-yl)-1-oxopent-4-en-2-yl]-3-phenylpropanamide 
• 1273504-05-4 (2S)-2-(2,2,2-trifluoroacetamido)-N-[1-(3,4-dihydroquinolin-1(2H)-yl)-4-iodo-1-oxopent-4-en-2-yl]-3-phenylpropanamide 

Relevant academic research and scientific papers

Palladium-catalyzed allylic alkylations as versatile tool for amino acid and peptide modifications

Palladium-catalyzed allylic alkylations are especially suitable for the introduction of γ,δ-unsaturated side chains into amino acids and even peptides. Glycine ester enolates are generally used as nucleophiles in these reactions, they react at a very low

Stereoselective palladium-catalyzed allylic alkylations of peptide amide enolates

Pd-catalyzed allylations are an excellent tool for stereoselective peptide modifications, being clearly superior to normal alkylations. The reactions proceed not only in high yield, but also high regio- and diastereoselectivities, and trans-products are f