127381-38-8Relevant articles and documents
Selenosulfonation of Conjugated Enynes and the Enyne Equivalent 1,4-Dichloro-2-butyne. Preparation of Sulfonyl-Substituted Allenic Alcohols and Dienes Using Sigmatropic Rearrangements and Organocuprate Additions
Back, Thomas G.,Lai, Enoch K. Y.,Muralidharan, K. Raman
, p. 4595 - 4602 (2007/10/02)
Conjugated enynes undergo free-radical selenosulfonation under either photochemical or thermal conditions with Se-phenyl p-tolueneselenosulfonate (1).Addition to the triple bond occurred preferentially with enynes having an acetylenic terminus (6-8) affor